The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Sulfur compounds / Organic S-compounds / CD3SOCD3 / Amaral(2004)_298K_190-240nm

DATAFILE: CD3SOCD3_Amaral(2004)_298K_190-240nm.txt
NAME: dimethyl-d6 sulfoxide, DMSO-d6
FORMULA: CD3SOCD3
AUTHOR(YEAR): Amaral(2004)
T: 298K
λ: 190-240nm
BIBLIOGRAPHY: G.A. Amaral, I. Torres, G.A. Pino, F.J. Aoiz, and L. Bañares, "Photodissociation dynamics of dimethyl sulfoxide-d6 at 210 nm: experimental evidence for a prompt anisotropic CD3 channel", Chem. Phys. Lett. 386, 419-424 (2004); DOI: 10.1016/j.cplett.2004.01.091
COMMENTS: Absorbances vs. wavelength shown in Fig. 1 have been digitized and scaled to σ(193 nm) = 9.4×10-18 cm2 molecule-1 and σ(222 nm) = 2.8×10-18 cm2 molecule-1 measured by

R. N. Rudolph, S. W. North, G. E. Hall, and T. J. Sears, "Diode laser measurements of CD3 quantum yields and internal energy for the dissociation of methyl sulfoxide-d6", J. Chem. Phys. 106, 1346-1352 (1997); DOI: 10.1063/1.473232

The datafile is the average of the two scalings

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